MICROENVIRONMENTAL EFFECTS IN SOLID-STATE REACTIONS - DISPERSIVE KINETICS OF CONFORMATION-DEPENDENT CHARGE DELOCALIZATION IN ALIPHATIC DIAMINE RADICAL CATIONS

被引：19

作者：

MARCINEK, A ^{[1
]}

GEBICKI, J ^{[1
]}

PLONKA, A ^{[1
]}

机构：

[1] TECH UNIV LODZ,INST APPL RADIAT CHEM,PL-90924 LODZ,POLAND

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 1990年 / 3卷 / 11期

关键词：

D O I：

10.1002/poc.610031110

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The kinetics of conformation‐dependent charge delocalization in radical cations generated from a series of α,ω‐diaminoalkanes, (CH3)2N(CH2)nN(CH3)2, (n = 1–3) in a 3‐methylpentane glassy solution at 90 K are discussed in terms of dispersive kinetics with the use of the time‐dependent rate constant in the form k(t) = Btα − 1. It was found that the activation energy distribution function became broader as the number of methylene groups separating the two nitrogen atoms increased, and that this process was accompanied by a substantial increase in the mean value of the activation energy. Copyright © 1990 John Wiley & Sons Ltd.

引用

页码：757 / 759

页数：3