A NOVEL ANTIFERROMAGNETICALLY COUPLED, DIMERIC, DODECANUCLEAR COPPER(II) COMPLEX INVOLVING 2 MACROCYCLIC LIGANDS EACH WITH A BENZENE-LIKE ARRANGEMENT OF 6 COPPER CENTERS

被引:45
作者
TANDON, SS [1 ]
THOMPSON, LK [1 ]
BRIDSON, JN [1 ]
机构
[1] MEM UNIV NEWFOUNDLAND,DEPT CHEM,ST JOHNS A1B 3X7,NEWFOUNDLAND,CANADA
关键词
D O I
10.1039/c39920000911
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Template condensation of 2,6-diformyl-4-methylphenol with 1,3-diamino-2-hydroxypropane, in the presence of copper(II) nitrate and a base, results in the formation of a novel dimeric, dodecacopper(II) complex of a 30-membered macrocyclic ligand (H6M), with a pseudo-hexagonal, 'benzene-like' arrangement of metal centres and an alternating double (mu(2)-OPh, mu(2)-OH) and single (mu(2)-OR) bridge arrangement within each ring.
引用
收藏
页码:911 / 913
页数:3
相关论文
共 14 条
[1]   SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF NI-4 AND ZN-4 COMPLEXES OF A MACROCYCLIC TETRANUCLEATING LIGAND [J].
BELL, M ;
EDWARDS, AJ ;
HOSKINS, BF ;
KACHAB, EH ;
ROBSON, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (10) :3603-3610
[2]   SYNTHESIS AND LIGATIONAL PROPERTIES OF THE 2 VERY LARGE POLYAZACYCLOALKANES [33]ANEN-11 AND [36]ANEN-12 FORMING TRINUCLEAR COPPER(II) COMPLEXES [J].
BENCINI, A ;
BIANCHI, A ;
GARCIAESPANA, E ;
MICHELONI, M ;
PAOLETTI, P .
INORGANIC CHEMISTRY, 1988, 27 (01) :176-180
[3]  
CORMARMOND J, 1985, J CHEM SOC CHEM COMM, P74
[4]   BINUCLEAR MANGANESE(II) AND NICKEL(II) COMPLEXES WITH A POTENTIALLY OCTADENTATE MACROCYCLIC LIGAND (H4L1) - SYNTHESIS AND CHARACTERIZATION - X-RAY CRYSTAL-STRUCTURES OF [MN2(H2L1)(CH3COO)2].2CH3OH AND [NI2(H2L1)(H2O)2CL2].2H2O [J].
DOWNARD, AJ ;
MCKEE, V ;
TANDON, SS .
INORGANICA CHIMICA ACTA, 1990, 173 (02) :181-190
[5]   A NEW TETRANUCLEATING TETRA-AMINO-TETRA-PHENOLIC MACROCYCLIC LIGAND AND THE CRYSTAL-STRUCTURE OF A ZN4 DERIVATIVE [J].
GRANNAS, MJ ;
HOSKINS, BF ;
ROBSON, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (22) :1644-1646
[6]   SYNTHESIS AND CRYSTAL-STRUCTURE OF A COMPLEX IN WHICH A SINGLE MACROCYCLIC LIGAND BINDS 6 CU-2 CENTERS IN A CYCLOHEXANE BOAT ARRANGEMENT [J].
HOSKINS, BF ;
ROBSON, R ;
SMITH, P .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (06) :488-489
[7]   THE X-RAY CRYSTAL-STRUCTURE AND SOME PROPERTIES OF A PLANAR TETRACOPPER(II) MACROCYCLIC COMPLEX CONTAINING A MU-4-HYDROXO BRIDGE [J].
MCKEE, V ;
TANDON, SS .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (05) :385-387
[8]   SYNTHESIS AND CHARACTERIZATION OF A SERIES OF TETRACOPPER(II) AND OCTA-COPPER(II) COMPLEXES WITH MACROCYCLIC LIGANDS [J].
MCKEE, V ;
TANDON, SS .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (02) :221-230
[9]   AN OCTACOPPER(II) COMPLEX WITH MU-5-OXO AND TRIPOD-LIKE PERCHLORATE LIGANDS - FORMATION AND X-RAY STRUCTURE OF THE [CU4(L)O(CLO4)]2(CLO4)2.2H2O DIMER [J].
MCKEE, V ;
TANDON, SS .
INORGANIC CHEMISTRY, 1989, 28 (15) :2901-2902