A NOVEL ANTIFERROMAGNETICALLY COUPLED, DIMERIC, DODECANUCLEAR COPPER(II) COMPLEX INVOLVING 2 MACROCYCLIC LIGANDS EACH WITH A BENZENE-LIKE ARRANGEMENT OF 6 COPPER CENTERS

被引：45

作者：

TANDON, SS ^{[1
]}

THOMPSON, LK ^{[1
]}

BRIDSON, JN ^{[1
]}

机构：

[1] MEM UNIV NEWFOUNDLAND,DEPT CHEM,ST JOHNS A1B 3X7,NEWFOUNDLAND,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 12期

关键词：

D O I：

10.1039/c39920000911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Template condensation of 2,6-diformyl-4-methylphenol with 1,3-diamino-2-hydroxypropane, in the presence of copper(II) nitrate and a base, results in the formation of a novel dimeric, dodecacopper(II) complex of a 30-membered macrocyclic ligand (H6M), with a pseudo-hexagonal, 'benzene-like' arrangement of metal centres and an alternating double (mu(2)-OPh, mu(2)-OH) and single (mu(2)-OR) bridge arrangement within each ring.

引用

页码：911 / 913

页数：3

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