BORATE ESTERS OF ALDITOLS - SYNTHESIS, STRUCTURE AND STABILITY IN AQUEOUS-SOLUTION

被引：2

作者：

MUNOZ, A

LAMANDE, L

机构：

来源：

CARBOHYDRATE RESEARCH | 1992年 / 225卷 / 01期

关键词：

D O I：

10.1016/0008-6215(92)80043-Z

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Borate esters were obtained by treating D,L-threitol, xylitol, L-arabinitol, 1,2:5,6-di-O-isopropylidene-D-mannitol, D-mannitol, D-glucitol, galactitol, and 1-deoxy-1-methylamino-D-glucitol with boric acid in water solution and in the presence of potassium hydroxide. Their structures were established by B-11- and C-13-n.m.r. spectroscopy. Spiranes obtained with glycerol, erythritol, and ribitol are unstable in water solution.

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页码：113 / 121

页数：9

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