MONTE-CARLO CALCULATION OF SOLUBILITIES OF HIGH-BOILING COMPONENT IN SUPERCRITICAL CARBON-DIOXIDE

被引：20

作者：

EYA, H ^{[1
]}

IWAI, Y ^{[1
]}

FUKUDA, T ^{[1
]}

ARAI, Y ^{[1
]}

机构：

[1] KYUSHU UNIV,FAC ENGN,DEPT CHEM ENGN,FUKUOKA 812,JAPAN

来源：

FLUID PHASE EQUILIBRIA | 1992年 / 77卷

关键词：

D O I：

10.1016/0378-3812(92)85098-S

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The test particle method proposed by Widom was applied to calculate the solubilities of naphthalene in supercritical carbon dioxide at 308.15 and 328.15 K. The Lennard-Jones (12-6) potential was used as the intermolecular potential and the Berthelot mixing rule was adopted for unlike molecular pairs. The calculated solubilities are in general higher than the experimental values of solubilities. However, by introducing an intermolecular interaction parameter between carbon dioxide and naphthalene, the calculation results showed good agreement with the experimental values.

引用

页码：39 / 51

页数：13

共 12 条

[1] DEVELOPMENT OF A 5-PARAMETER CUBIC EQUATION OF STATE [J].