STEREOCHEMICAL STUDIES ON THE ADDITION OF ALLYLSILANES TO ALDEHYDES - THE S-E' COMPONENT

被引：67

作者：

DENMARK, SE

ALMSTEAD, NG

机构：

[1] Roger Adams Laboratory, Department of Chemistry, University of Illinois, Urbana

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 18期

关键词：

D O I：

10.1021/jo00097a008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Compounds (l)-1 and (u)-1 have revealed both the position of the silicon electrofuge and the relative orientation of the double bonds in the allylmetal-aldehyde addition. Cyclization was found to proceed with high selectivity via an anti SEI pathway regardless of the proximal/distal ratio.

引用

页码：5130 / 5132

页数：3

共 61 条

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