PROBING ACTIVE-SITES IN SOLID CATALYSTS FOR THE LIQUID-PHASE EPOXIDATION OF ALKENES

被引：79

作者：

SANKAR, G

REY, F

THOMAS, JM

GREAVES, GN

CORMA, A

DOBSON, BR

DENT, AJ

机构：

[1] UCL ROYAL INST GREAT BRITAIN, DAVY FARADAY RES LAB, LONDON W1X 4BS, ENGLAND

[2] EPSRC, DARESBURY LAB, WARRINGTON WA4 4AD, CHESHIRE, ENGLAND

[3] UNIV POLITECN VALENCIA, INST TECNOL QUIM, E-46071 VALENCIA, SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 19期

关键词：

D O I：

10.1039/c39940002279

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using X-ray absorption fine structure measurements with a synchrotron source, the local environment of the titanium-centred active site of a siliceous mesoporous catalyst for the epoxidation of cyclohexene by H2O2 has been determined prior to the onset and during the course of catalysis.

引用

页码：2279 / 2280

页数：2

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