[NPR(N)4]2[RES4)CU5I6] AND [NET4]2[(RES4)CU3I4] - NOVEL LOW DIMENSIONAL SOLIDS

被引：30

作者：

MULLER, A

KRICKEMEYER, E

HILDEBRAND, A

BOGGE, H

SCHNEIDER, K

LEMKE, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 23期

关键词：

D O I：

10.1039/c39910001685

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compounds [NPrn4]2[(ReS4)Cu5I6] 1 and [NEt4]2[(ReS4)Cu3I4] 2, containing polymeric heterometallic chains and interesting structural features according to X-ray structure analyses, have been obtained by reaction of Cul with [NPrn4][ReS(S4)2] in dichloromethane 1 or [NEt4][ReS4] 2 in acetone; complexes 1 and 2 are examples of a series of compounds which prove the possibility of a stepwise 'capping' of the edges of an ReS4 tetrahedron by a Cu(hal/pseudohal)x fragment (x = 1,2).

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页码：1685 / 1687

页数：3

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