FORMATION OF INORGANIC QUASI-CYCLIC STRUCTURES THROUGH SECONDARY INTERACTION - A FEW CASES OF HETEROGEOMETRISM

被引：10

作者：

HAIDUC, I ^{[1
]}

机构：

[1] UNIV BABES BOLYAI,FAC CHIM,CLUJ NAPOCA,ROMANIA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 93卷 / 1-4期

关键词：

D O I：

10.1080/10426509408021850

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rings formed by secondary interactions are called quasi-cyclic structures. Examples are given mainly from the field of dithiophosphorus ligand derivatives of Main Group metals, which may dimerize with formation of quasi-cyclic structures. Intramolecular cyclization and supramolecular association through secondary bands leading to formation of quasi-cycles, is also cited. In several cases cyclic compounds of the same general formula contain metal atoms in different coordination geometries. The term heterogeometrism is suggested to describe this situation. The corresponding compounds are calledheterogeometric analogues.

引用

页码：345 / 348

页数：4

共 13 条

[1]

Alcock N.W., 1972, ADV INORG CHEM RAD, V15, P1, DOI DOI 10.1016/S0065-2792(08)60016-3

[2] THE CRYSTAL-STRUCTURES OF THE DIPHENYLDITHIOPHOSPHINATES OF ANTIMONY(III) AND BISMUTH(III) - SB(S2PPH2)3, BI(S2PPH2)3 [J].