ON THE BEHAVIOR OF COTSPC AS ELECTRO-CATALYST FOR OXYGEN REDUCTION IN DMF SOLUTIONS

被引：4

作者：

HUANG, CB

LIU, XD

机构：

[1] Department of Chemistry, Jilin University, Changchun

来源：

ELECTROCHIMICA ACTA | 1990年 / 35卷 / 01期

关键词：

D O I：

10.1016/0013-4686(90)85055-R

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The CoTSPc (cobalt tetra-sulfonated phthalocyanine) adsorbed on either a quasi-reversible OPG (ordinary pyrolytic graphite) electrode or a totally irreversible Pb electrode showed no catalytic effect toward O2 reduction in DMF (dimethylformamide) solution. Introducing some water into the DMF electrolyte did not improve the catalytic activity. These effects are attributed to the lack of oxidation-reduction circulation between Co(I)/Co(II) and O2/O-2 in the media studied. © 1990.

引用

页码：173 / 175

页数：3

共 12 条

[1]

BARD AJ, 1980, ELECTROCHEMICAL METH, P224

[2] ELECTRODE CATALYSIS OF THE 4-ELECTRON REDUCTION OF OXYGEN TO WATER BY DICOBALT FACE-TO-FACE PORPHYRINS [J].