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SPECTROCHEMICAL PROPERTIES OF NONCUBIC TRANSITION-METAL COMPLEXES IN SOLUTIONS .4. ENERGY-LEVELS OF TETRAGONAL DISTORTED CHROMIUM(III) COMPLEXES IN AQUEOUS-SOLUTIONS

被引：23
作者：
KURZAK, K
机构：
[1] Institute of Chemistry, Pedagogical University
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1991年 / 47卷 / 08期
关键词：
D O I：
10.1016/0584-8539(91)80034-G
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
A general method for the analysis of the d-d transition energies observed in the ligand field spectra of chromium(III) complexes with D4h or C4v symmetry is described and used to derive the crystal field and angular overlap parameters for the complexes of known stereochemistry. Examples are also presented. The spectrum of the diamminetetrakis(isothiocyanato)chromate(III) ammonium in aqueous solution is reported. The spectra of the miscellaneous systems have been studied theoretically using a crystal field model and an angular overlap model.
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页码：1041 / 1050
页数：10
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