ELECTRONIC STRUCTURE OF NON-ALTERNANT HYDROCARBONS - THEIR ANALOGUES AND DERIVATIVES .18. ELECTRONIC SPECTRUM AND ELECTRON AFFINITY OF FLUORANTHENE

被引：36

作者：

MICHL, J

机构：

[1] Department of Chemistry, University of Houston, Houston

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1969年 / 30卷 / 01期

关键词：

D O I：

10.1016/0022-2852(69)90236-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

A comparison of the fine structure of the absorption spectrum of fluoranthene and seven of its simple derivatives recorded at 77°K reveals the presence of seven separate electronic transitions below 43 000 cm-1. Evidence for the existence of three additional transitions in the 43 000-50 000 cm-1 region is also presented. Gas phase electron affinity is reported. The results are in good agreement with semiempirical π-electron calculations. © 1969.

引用

收藏

页码：66 / &

相关论文

共 16 条

[1] COMPREHENSIVE SPECTROSCOPIC INVESTIGATION OF POLYNUCLEAR AROMATIC HYDROCARBONS .1. ABSORPTION SPECTRA AND STATE ASSIGNMENTS FOR TETRACYCLIC HYDROCARBONS AND THEIR ALKYL-SUBSTITUTED DERIVATIVES [J].

BECKER, RS ;

SINGH, IS ;

JACKSON, EA .

JOURNAL OF CHEMICAL PHYSICS, 1963, 38 (09) :2144-&

[2] EXTENSION OF ELECTRON AFFINITIES AND IONIZATION POTENTIALS OF AROMATIC HYDROCARBONS [J].

BECKER, RS ;

CHEN, E .

JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (07) :2403-&

[3] ELECTRON AFFINITIES OF AROMATIC HYDROCARBONS IN GAS PHASE AND IN SOLUTION [J].

CHAUDHURI, J ;

JAGURGRO.J ;

SZWARC, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (09) :3063-+

[4]

CLAR E, 1964, POLYCYCLIC HYDROCARB, V1, P94

[5] ELECTRONIC SPECTRA OF ACENAPHTHYLENE AND FLUORANTHENE - A COMMENT ON CLASSIFICATION OF ELECTRONIC SPECTRA [J].

HEILBRONNER, E ;

WEBER, JP ;

MICHL, J ;

ZAHRADNIK, R .

THEORETICA CHIMICA ACTA, 1966, 6 (02) :141-+

[6]

JAFFE HH, 1962, THEORY APPLICATIONS, P343

[7] CALCULATION OF ELECTRONIC SPECTRA OF NONALTERNANT CONJUGATED HYDROCARBONS BY SEMIEMPIRICAL METHOD OF LIMITED CONFIGURATION INTERACTION [J].

KOUTECKY, J ;

HOCHMAN, P ;

MICHL, J .

JOURNAL OF CHEMICAL PHYSICS, 1964, 40 (09) :2439-&

[8]

Mataga N., 1957, Z PHYS CHEM, V13, P140, DOI [10.1524/zpch.1957.13.3_4.140, DOI 10.1524/ZPCH.1957.13.3_4.140]

[9] A NOTE ON ABSENCE OF A HYPSOCHROMIC SHIFT IN PROTONATED AMINOFLUORANTHENES [J].

MICHL, J .

SPECTROCHIMICA ACTA, 1965, 21 (12) :2146-&

[10] ELECTRONIC STRUCTURE OF NON-ALTERNANT HYDROCARBONS THEIR ANALOGUES AND DERIVATIVES .15. AN HMO STUDY OF AMINO NITRO AND AZA DERIVATIVES OF FLUORANTHENE [J].

MICHL, J ;

ZAHRADNI.R .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1966, 31 (09) :3478-&