SCHIFF-BASE COMPLEXES OF ORGANOTIN(IV) - INFRARED AND MOSSBAUER STUDIES ON THE ADDITION COMPLEXES OF DIORGANOTIN DICHLORIDES WITH N-ALKYL(ARYL)SALICYLIDENEIMINES

被引：47

作者：

SARASWAT, BS

SRIVASTAVA, G

MEHROTRA, RC

机构：

[1] Chemical Laboratories, University of Rajasthan, Jaipur

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 164卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)86699-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fourteen new addition complexes of the type R2SnCl2 · 2 HOC6H4CHNR′ have been synthesized by the reactions of diorganotin dichlorides, R2SnCl2 (where R = Me, Et, n-Bu and Ph), with N-alkyl(aryl)salicylideneimines, HOC6H4CHNR′ (where R′ = Me, Et, n-Bu and Ph), in non-aqueous solvents. The complexes are non-electrolytes in nitrobenzene. Infrared and Mössbauer spectroscopic studies indicate an all-trans octahedral geometry for the complexes. © 1979.

引用

页码：153 / 158

页数：6

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