CARBANIONS OF S-ALKANOATE-O,O-DIALKYL PHOSPHATES - NEW SYNTHONS FOR REACHING ALPHA,BETA-ETHYLENIC ESTERS

被引：11

作者：

BABOULENE, M ^{[1
]}

STURTZ, G ^{[1
]}

机构：

[1] FAC SCI & TECH,CHIM HETEROORGAN,EQUIPE RECH 612,6 AVE LE GORGEU,F-29283 BREST,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 177卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)92328-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The stabilization of phosphorothiolate carbanions has been achieved. Condensation of these carbanions with carbonyl derivatives lead to the corresponding α,β-unsaturated esters; a mechanism, via a β-hydroxyphosphorothiolate-β-mercaptophosphate rearrangement, is described. These new synthons are compared with the phosphonate analogs (Wittig-Horner's reagent). © 1979.

引用

页码：27 / 34

页数：8

共 14 条

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[5] MULLER E, 1964, HOUBEN WEYL, V12
[6] SMALL-RING HETEROCYCLIC COMPOUNDS .3. REACTIONS OF AROMATIC GLYCIDIC ESTERS WITH THIOUREA AND THIOACETIC ACID
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[7] SAVIGNAC P, 1974, CR ACAD SCI C CHIM, V279, P609
[8] SAVIGNAC P, 1978, B SOC CHIM FR, P1506
[9] STURTZ G, 1973, CR ACAD SCI C CHIM, V276, P1807
[10] STURTZ G, 1973, CR ACAD SCI C CHIM, V277, P395

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