SYNTHESIS AND CRYSTAL-STRUCTURE OF MOLYBDENUM-TRISUBSTITUTED TUNGSTOPHOSPHATE ANION SALT, A-BETA-[N(CH3)4]3[PMO3W9O40]

被引：25

作者：

KAWAFUNE, I ^{[1
]}

MATSUBAYASHI, GE ^{[1
]}

机构：

[1] OSAKA UNIV, COLL GEN EDUC, INST CHEM, TOYONAKA, OSAKA 560, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 09期

关键词：

D O I：

10.1246/cl.1992.1869

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molybdenum-trisubstituted tungstophosphate anion, [PMo3W9O40]3-, was synthesized by a reaction of Na2MoO4 and A-Na9[PW9O34] in an HCl and 1,4-dioxane mixed solution. X-ray crystal structure analysis of the tetramethylammonium salt of the mixed addenda polyanion revealed the anion geometry as an A-type trisubstituted, beta-isomer.

引用

页码：1869 / 1872

页数：4

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