ELECTROOPTIC EFFECT IN LANGMUIR-BLODGETT-FILMS OF 2-(DOCOSYLAMINO)-5-NITROPYRIDINE PROBED BY SURFACE-PLASMON WAVES

被引：17

作者：

WIJEKOON, WMKP

ASGHARIAN, B

CASSTEVENS, M

SAMOC, M

TALAPATRA, GB

PRASAD, PN

GEISLER, T

ROSENKILDE, S

机构：

[1] SUNY BUFFALO,DEPT CHEM,PHOTON RES LAB,BUFFALO,NY 14260

[2] TECH UNIV DENMARK,APPL MATH PHYS LAB,DK-2800 LYNGBY,DENMARK

来源：

LANGMUIR | 1992年 / 8卷 / 01期

关键词：

D O I：

10.1021/la00037a026

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Measurements of electrooptic modulation of surface plasmon resonance have been carried out on horizontally transferred Langmuir-Blodgett films of 2-(docosylamino)-5-nitropyridine. The observed Pockels response is approximately constant for different numbers of layers in multilayered films and is proportional to the strength of the modulating field. The calculated second-order susceptibility values are approximately 2 x 10(-13) m V-1, 2 orders of magnitude lower than those derived from second harmonic generation studies. The presence of the Pockels effect is attributed to off-diagonal terms in the second-order susceptibility.

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页码：135 / 139

页数：5

相关论文

共 17 条

[1] OPTICAL WAVE-GUIDING AND NONLINEAR OPTICS IN HIGH-QUALITY 2-DOCOSYLAMINO-5-NITROPYRIDINE LANGMUIR-BLODGETT-FILMS [J].

BOSSHARD, C ;

KUPFER, M ;

GUNTER, P ;

PASQUIER, C ;

ZAHIR, S ;

SEIFERT, M .

APPLIED PHYSICS LETTERS, 1990, 56 (13) :1204-1206

[2]

BOSSHARD C, 1988, P SOC PHOTOOPT INSTR, V1017, P141

[3] FACTORS INFLUENCING THE ENHANCEMENT OF RAMAN SPECTRAL INTENSITY FROM A ROUGHENED SILVER SURFACE - THE ADSORPTION AND SURFACE RAMAN-SCATTERING OF 2-AMINO 5-NITRO PYRIDINE [J].

BUSBY, CC ;

CREIGHTON, JA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 133 (01) :183-193

[4]

Chemia D. S., 1987, NONLINEAR OPTICAL PR

[5] OPTICALLY NONLINEAR LANGMUIR-BLODGETT-FILMS - LINEAR ELECTROOPTIC PROPERTIES OF MONOLAYERS [J].

CROSS, GH ;

GIRLING, IR ;

PETERSON, IR ;

CADE, NA ;

EARLS, JD .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1987, 4 (06) :962-967

[6] LINEAR POCKELS RESPONSE OF A MONOLAYER LANGMUIR-BLODGETT-FILM [J].

CROSS, GH ;

GIRLING, IR ;

PETERSON, IR ;

CADE, NA .

ELECTRONICS LETTERS, 1986, 22 (21) :1111-1112

[7] OPTICAL 2ND-HARMONIC GENERATION IN LANGMUIR-BLODGETT FILMS OF 2-DOCOSYLAMINO-5-NITROPYRIDINE [J].

DECHER, G ;

TIEKE, B ;

BOSSHARD, C ;

GUNTER, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (14) :933-934

[8] 2ND-ORDER NON-LINEAR OPTICAL EFFECTS IN LANGMUIR-BLODGETT FILMS [J].

GIRLING, IR ;

JETHWA, SR ;

STEWART, RT ;

EARLS, JD ;

CROSS, GH ;

CADE, NA ;

KOLINSKY, PV ;

JONES, RJ ;

PETERSON, IR .

THIN SOLID FILMS, 1988, 160 (1-2) :355-362

[9]

Hurst M., 1986, Journal of Molecular Electronics, V2, P35

[10] SURFACE RAMAN SPECTROELECTROCHEMISTRY .1. HETEROCYCLIC, AROMATIC, AND ALIPHATIC-AMINES ADSORBED ON ANODIZED SILVER ELECTRODE [J].

JEANMAIRE, DL ;

VANDUYNE, RP .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1977, 84 (01) :1-20