SPECTRAL ASSIGNMENT OF 2''-O-BETA-D-GLUCOPYRANOSYLSAIKOSAPONIN-B2 BY 2-DIMENSIONAL NMR TECHNIQUES

被引：13

作者：

LIN, LZ

LIN, LJ

CORDELL, GA

LUO, SQ

JIANG, HF

机构：

[1] UNIV ILLINOIS HOSP,COLL PHARM,DEPT MED CHEM & PHARMACOGNOSY,CHICAGO,IL 60612

[2] SHANGHAI INST PHARMACEUT IND,SHANGHAI,PEOPLES R CHINA

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1992年 / 30卷 / 11期

关键词：

TRITERPENE SAPONIN; 2''-O-BETA-D-GLUCOPYRANOSYLSAIKOSAPONIN B2; SEPARATION; STRUCTURE ELUCIDATION; BUPLEURUM-LONGICAULE; NMR ASSIGNMENT; 2D-NMR; (DQF-COSY; ROESY; HOHAHA; HETCOR; HMBC);

D O I：

10.1002/mrc.1260301113

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new derivative of saikosaponin was isolated from the roots of Bupleurum longicaule and identified as 2"-O-beta"-D-glucopyranosylsaikosaponin b2. Its H-1 and C-13 NMR data and the connectivities of the sugar moiety were assigned by use of a combination of two-dimensional NMR techniques (DQF-COSY, HOHAHA, ROESY, HETCOR and HMBC).

引用

页码：1097 / 1103

页数：7

共 40 条

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