EFFICIENT CLEAVAGE OF CARBON GRAPHENE LAYERS BY OXIDANTS

被引：79

作者：

HWANG, KC

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 02期

关键词：

D O I：

10.1039/c39950000173

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The graphene layers at carbon nanotube cap regions are efficiently cleaved by several oxidants (e.g, KMnO4, OsO4 and RuO4) in acidic solution at 100 degrees C, but not by stronger oxidants, such as K2Cr2O7-H+ and H2O2-H+.

引用

页码：173 / 174

页数：2

共 24 条

[1] CAPILLARITY-INDUCED FILLING OF CARBON NANOTUBES [J].

AJAYAN, PM ;

IIJIMA, S .

NATURE, 1993, 361 (6410) :333-334

[2] OPENING CARBON NANOTUBES WITH OXYGEN AND IMPLICATIONS FOR FILLING [J].

AJAYAN, PM ;

EBBESEN, TW ;

ICHIHASHI, T ;

IIJIMA, S ;

TANIGAKI, K ;

HIURA, H .

NATURE, 1993, 362 (6420) :522-525

[3] USE OF RUTHENIUM TETROXIDE AS A MULTI-PURPOSE OXIDANT [J].

BERKOWITZ, LM ;

RYLANDER, PN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 80 (24) :6682-6684

[4]

CAPUTO JA, 1967, TETRAHEDRON LETT, V47, P4729

[5] A GREATLY IMPROVED PROCEDURE FOR RUTHENIUM TETRAOXIDE CATALYZED OXIDATIONS OF ORGANIC-COMPOUNDS [J].

CARLSEN, PHJ ;

KATSUKI, T ;

MARTIN, VS ;

SHARPLESS, KB .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (19) :3936-3938

[6] FATTY ACIDS .8. PARTIAL OXIDATION OF UNSATURATED ACIDS WITH PERFORMIC ACID, AND A NEW METHOD OF DETERMINING STRUCTURE OF NON-CONJUGATED POLYETHENOID ACIDS [J].

GUNSTONE, FD ;

SYKES, PJ .

JOURNAL OF THE CHEMICAL SOCIETY, 1962, (AUG) :3058-&

[7] CHEMISTRY OF THE FULLERENES - THE MANIFESTATION OF STRAIN IN A CLASS OF CONTINUOUS AROMATIC-MOLECULES [J].

HADDON, RC .

SCIENCE, 1993, 261 (5128) :1545-1550

[8] PI-ELECTRONS IN 3 DIMENSIONS [J].

HADDON, RC .

ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (06) :243-249

[9] OPTICALLY-ACTIVE CARBON - KINETIC RESOLUTION OF C(76) BY ASYMMETRIC OSMYLATION [J].

HAWKINS, JM ;

MEYER, A .

SCIENCE, 1993, 260 (5116) :1918-1920

[10] OSMYLATION OF C(70) - REACTIVITY VERSUS LOCAL CURVATURE OF THE FULLERENE SPHEROID [J].

HAWKINS, JM ;

MEYER, A ;

SOLOW, MA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (16) :7499-7500

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