A MODEL FOR THE THERMAL AND CHEMORHEOLOGICAL BEHAVIOR OF THERMOSET PROCESSING .2. UNSATURATED POLYESTER BASED COMPOSITES

被引：89

作者：

KENNY, JM

MAFFEZZOLI, A

NICOLAIS, L

机构：

[1] Facolta di Ingegneria, Universita degli Studi di Napoli, 80125 Napoli, Piazzale Tecchio

来源：

COMPOSITES SCIENCE AND TECHNOLOGY | 1990年 / 38卷 / 04期

关键词：

D O I：

10.1016/0266-3538(90)90020-6

中图分类号：

TB33 [复合材料];

学科分类号：

摘要：

The rheological and thermokinetic aspects of the cure of unsaturated polyester based composites are analyzed by means of a computer program developed by using the heat transfer and heat generation characteristics of polymerizable systems. The temperature and extent of reaction profiles, calculated according to an appropriate kinetic and heat transfer model, have been used to predict the corresponding viscosities by an empirical model. A commercial polyester system commonly used in resin transfer molding. (RTM) has been characterized by differential scanning calorimetry (DSC) and dynamic viscosity measurements and the results have been processed to construct the corresponding sub-model. Experimental temperature profiles measured during the processing of the systems studied are compared with theoretical values obtained from the master model. © 1990.

引用

页码：339 / 358

页数：20

共 24 条

[1]

APICELLA A, 1986, DEV REINFORCED PLAST, V5, P151

[2] THE STEFAN AND DEBORAH NUMBERS IN POLYMER CRYSTALLIZATION [J].