FERROTETRAPHENYLPORPHYRIN COMPLEXES WITH CHLOROCARBENES CONTAINING ELECTROPHILIC GROUP - IRON(II)(TPP)(CCLA), A=CN OR COOC2H5

被引：46

作者：

MANSUY, D

GUERIN, P

CHOTTARD, JC

机构：

[1] Laboratoire de chimie, l'Ecole Normale Supérieure, associé au C.N.R.S., 75231 Paris Cédex 05, 24, rue Lhomond

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 171卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)81540-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stable iron(II) carbene complexes with a chlorocarbene having an electron-withdrawing group CClA (A = CN and COOC2H5 have been isolated. These complexes have been prepared by reduction of CCl3COOC2H5 and CCl3CN with the iron tetraphenylporphyrin iron(II)(TPP) in the presence of an excess of reducing agent. The structure of these complexes is established by study of their IR, 1H and 13C NMR and mass spectra. Their properties are compared with those of the corresponding carbene complex iron(II)(TPP)(CCl2). © 1979.

引用

页码：195 / 201

页数：7

共 17 条

[1] CONCERNING MESO-TETRAPHENYLPORPHYRIN PURIFICATION [J].

BARNETT, GH ;

HUDSON, MF ;

SMITH, KM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (14) :1401-1403

[2] BINDING OF IMIDAZOLE AND 2-METHYLIMIDAZOLE BY HEMES IN ORGANIC-SOLVENTS - EVIDENCE FOR 5-COORDINATION [J].

BRAULT, D ;

ROUGEE, M .

BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 1974, 57 (03) :654-659

[3] ISOLATION OF STABLE SECONDARY CATIONIC IRON CARBENE COMPLEXES ETA-5-C5H5(CO)2FECHC6H5PF6 AND "ETA-5-C5H5(CO)[P(C6H5)3]FECHC6H5PF6 [J].

BROOKHART, M ;

NELSON, GO .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (18) :6099-6101

[4]

Fischer E. O., 1976, ADV ORGANOMETALLIC C, V14, P1

[5] TRANSITION METAL-CARBENE COMPLEXES .94. PENTACARBONYL(DIETHYLAMINOFLUOROCARBENE)CHROMIUM [J].

FISCHER, EO ;

KLEINE, W ;

KREISSL, FR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1976, 15 (10) :616-617

[6]

FISCHER EO, 1977, J ORGANOMET CHEM, V129, P197

[7] TRANSITION METAL-CARBENE COMPLEXES .106. BROMO(DIETHYLAMINO)CARBENEPENTACARBONYLCHROMIUM, IODO(DIETHYLAMINO)CARBENEPENTACARBONYLCHROMIUM, ISOCYANATO(DIETHYLAMINO)CARBENEPENTACARBONYLCHROMIUM AND ISOTHIOCYANATO(DIETHYLAMINO)CARBENEPENTACARBONYLCHROMIUM [J].

FISCHER, EO ;

KLEINE, W ;

KREISSL, FR ;

FISCHER, H ;

FRIEDRICH, P ;

HUTTNER, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 128 (03) :C49-C53

[8]

FISCHER EO, 1976, J ORGANOMET CHEM, V107, pC23, DOI 10.1016/S0022-328X(00)91547-X

[9] THERMODYNAMIC AND KINETIC PROPERTIES OF AN IRON-PORPHYRIN SYSTEM [J].

FLEISCHER, EB ;

PALMER, JM ;

SRIVASTAVA, TS ;

CHATTERJEE, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (13) :3162-+

[10] TRANSITION-METAL CHEMISTRY OF "DICHLOROMETHYLENE(DIMETHYL)AMMONIUM CHLORIDE - C-CHLOROCARBENE COMPLEXES [J].

HARTSHORN, AJ ;

LAPPERT, MF ;

TURNER, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (23) :929-930

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