IMPACT OF NONUNIFORM COUNTERION CONDENSATION ON THE GROWTH OF LINEAR CHARGED MICELLES

被引：20

作者：

ODIJK, T

机构：

[1] Department of Polymer Technology, Faculty of Chemical Engineering and Materials Science, Delft University of Technology, 2600 GA Delft

来源：

PHYSICA A | 1991年 / 176卷 / 02期

关键词：

D O I：

10.1016/0378-4371(91)90287-M

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

At low ionic strength counterions cluster nonuniformly around a linear, highly charged micelle. The micelle is regarded as a finite line charge with relatively fewer counterions condensing on the two ends. The end contribution to the electrostatic free energy is positive, so that the micelles shorten upon addition of simple salt to the solution.

引用

页码：201 / 205

页数：5

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