POTASSIUM TETRAPHENYLIMIDODIPHOSPHINATE COMPLEX OF 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE AN INORGANIC (CARBON-FREE) CHELATE RING

被引：16

作者：

CEAOLIVARES, R

MUNOZ, MA

机构：

[1] Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria

来源：

MONATSHEFTE FUR CHEMIE | 1993年 / 124卷 / 05期

关键词：

ALKALINE COMPLEXES; CROWN ETHER COMPLEXES; IMIDODIPHOSPHINATE CHELATES; INORGANIC RINGS; PHOSPHAZENE HETEROCYCLES;

D O I：

10.1007/BF00819515

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Potassium tetraphenylimidodiphosphinate, [K][Ph2P(O)NP(O)Ph2], reacts with 18-crown-6 ether to give the monohydrated complex [K(18-crown-6][Ph2P(O)NP(O)Ph2].H2O. The compound shows an interaction potassium oxygen, forming an inorganic (carbon free) chelate ring and it is different to the sulphur homolog which has no interaction cation anion.

引用

页码：471 / 476

页数：6

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