A NEW APPROACH TO HYDROAZULENES VIA OLEFIN METATHESIS

被引：24

作者：

JUNGA, H ^{[1
]}

BLECHERT, S ^{[1
]}

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,STR DES 17 JUNI 135,W-1000 BERLIN 12,GERMANY

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 23期

关键词：

D O I：

10.1016/S0040-4039(00)79212-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several functionalized diolefins cyclize to hydroazulenes (among others) via olefin metathesis with CH3ReO3. These conversions are regioselective and occur with high diastereoselectivity.

引用

页码：3731 / 3732

页数：2

共 7 条

[1] INTRAMOLECULAR ALKYLATION OF CYCLOPENTENONES - A GENERAL-ROUTE TO CONJOINT RING-SYSTEMS [J].

ANTCZAK, K ;

KINGSTON, JF ;

ALWARD, SJ ;

FALLIS, AG .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1984, 62 (05) :829-837

[2] HYDROBORATION .70. THE POLYCYCLIC HYDROBORATION OF ACYCLIC AND CYCLIC TRIENES WITH BORANE IN TETRAHYDROFURAN AND TRIETHYLAMINE-BORANE - REEXAMINATION OF THE STEREOCHEMISTRY OF ISOMERIC PERHYDRO-9B-BORAPHENALENES [J].

BROWN, HC ;

NEGISHI, E ;

DICKASON, WC .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (04) :520-527

[3] SIMPLE AND EFFICIENT SYNTHESIS OF METHYLTRIOXORHENIUM (VII) - A GENERAL-METHOD [J].

HERRMANN, WA ;

KUHN, FE ;

FISCHER, RW ;

THIEL, WR ;

ROMAO, CC .

INORGANIC CHEMISTRY, 1992, 31 (21) :4431-4432

[4] APPLICATION OF CARBONYL UMPOLUNG TO PROSTAGLANDIN SYNTHESIS .3. SYNTHESIS OF 11-DEOXY PROSTAGLANDIN SYNTHONS [J].

NOVAK, L ;

BAAN, G ;

MAROSFALVI, J ;

SZANTAY, C .

CHEMISCHE BERICHTE-RECUEIL, 1980, 113 (09) :2939-2949

[5] TOTAL SYNTHESIS OF DL-PENTALENOLACTONE [J].

PARSONS, WH ;

SCHLESSINGER, RH ;

QUESADA, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (02) :889-890

[6] SYNTHESIS OF MACROLIDES BY METATHESIS [J].

VILLEMIN, D .

TETRAHEDRON LETTERS, 1980, 21 (18) :1715-1718

[7]

WILSON SE, 1975, TETRAHEDRON LETT, V16, P4651

← 1 →