CONFORMATIONAL-ANALYSES FOR ACETYL AND FORMYL LIGANDS BOUND TO TRANSITION-METAL AUXILIARIES

被引：10

作者：

DAVIES, SG

SMALLRIDGE, AJ

机构：

[1] The Dyson Perrins Laboratory, University of Oxford, Oxford, OX1 3QY, South Parks Road

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 397卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)85324-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Conformational analyses for acetyl and formyl ligands bound to transition metal auxiliaries reveal that, after considering primary stereoelectronic effects where appropriate, the conformations adopted by acetyl ligands are determined primarily by steric interactions while the corresponding formyl conformations are determined primarily by dipolar and electrostatic forces. No evidence for secondary stereoelectronic effects is apparent. © 1990.

引用

页码：C13 / C19

页数：7

共 14 条

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