CHARACTERIZATION OF THE UV, VISIBLE AND NEAR-IR SPECTRA OF THE FULLERIDE ANIONS C-60(1-), C-60(2-) AND C-60(3-), AND THEORETICAL-ANALYSIS OF THE SPECTRA OF C-60(1+), C-60(0), C-60(1-), C-60(2-) AND C-60(3-) BY SELF-CONSISTENT FIELD-X-ALPHA-SCATTERED-WAVE (SCF-X-ALPHA-SW) CALCULATIONS

被引：111

作者：

HEATH, GA ^{[1
]}

MCGRADY, JE ^{[1
]}

MARTIN, RL ^{[1
]}

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 17期

关键词：

D O I：

10.1039/c39920001272

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The spectra of the electrogenerated C60(2-), and C60(3-) ions reveal intense near-IR absorption bands similar to those observed in C60(1-); theoretical analysis of the spectra of C60z species (z = 1+, 0, 1-,2-,3-) by SCF-X-alpha-SW calculations provides an explicit interpretation of the strong bands in the UV region, and establishes the nature of the characteristic near-IR bands observed for the cationic and anionic species.

引用

页码：1272 / 1274

页数：3

共 25 条

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