EPR OBSERVATION OF A RADICAL-CATION SALT DERIVED FROM HEXAMETHYL(DEWAR BENZENE) AT ROOM-TEMPERATURE

被引：5

作者：

ROTH, HD ^{[1
]}

LAKKARAJU, P ^{[1
]}

ZHANG, JX ^{[1
]}

机构：

[1] RUTGERS STATE UNIV,DEPT CHEM,WRIGHT RIEMAN LABS,NEW BRUNSWICK,NJ 08855

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 17期

关键词：

D O I：

10.1039/c39940001969

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vapour deposition of hexamethyl(Dewar benzene) or hexamethylprismane onto solid dioxygenyl hexafluoroantimonate at liquid nitrogen temperature followed by warming the sample to room temperature gives rise to 13-line EPR spectra with binomial intensities (g = 2.0025 +/- 0.0004; A = 10.7 +/- 0.1 G), which are very similar to the spectra previously observed at cryogenic temperatures upon radiolysis of hexamethyl(Dewar benzene).

引用

页码：1969 / 1970

页数：2

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