Ion-pair effects in electrochemistry of aromatic compounds influence of supporting electrolyte cations on half-wave potentials of the ketone-ketyl radical anion systems

被引：76

作者：

Kalinowski, M. K. ^{[1
]}

机构：

[1] Univ Warsaw, Dept Chem, PL-22 Warsaw, Poland

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 7卷 / 01期

关键词：

D O I：

10.1016/0009-2614(70)80247-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of supporting electrolyte cations on the polarographic reduction of benzophenone and fluorenone in dimethylformamide (DMF) was studied. The experimental equation E-1/2 = E-1/2(0) + mu Phi has been proposed for half-wave potential of investigated ketones in the presence of various cations. where Phi is the ionic potential of the cation.

引用

页码：55 / 56

页数：2

共 9 条

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GIVEN, PH
PEOVER, ME
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[4] KALINOWSKI MK, IN PRESS B ACAD POLO
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[7] Peover M.E., 1963, J ELECTROANAL CHEM, V6, P46
[8] PEOVER ME, 1964, 3 INT C POL SOUTH, P1003
[9] POLAROGRAPHIC STUDIES IN ACETONITRILE AND DIMETHYLFORMAMIDE .3. BEHAVIOR OF QUINONES AND HYDROQUINONES
WAWZONEK, S
BERKEY, R
BLAHA, EW
RUNNER, ME
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1956, 103 (08) : 456 - 459

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