ASPECTS OF THE ADDITION OF IODINE(I) AZIDE TO ALKENES

被引：11

作者：

CAMBIE, RC

HAYWARD, RC

RUTLEDGE, PS

SMITHPALMER, T

SWEDLUND, BE

WOODGATE, PD

机构：

[1] Department of Chemistry, University of Auckland, Auckland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 01期

关键词：

D O I：

10.1039/p19790000180

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iodine(I) azide, formed from sodium azide-iodine(I) chloride, exists in acetonitrile as a complex with sodium azide. Addition of iodine(I) azide to cyclohexene gives a cis-iodo-azide as well as the expected trans-adduct. The addition of iodine(I) azide to a mixture of (Z)- and (E)-[β- 2H]styrene occurs in a stereospecific manner. In contrast to a literature report, the addition of iodine(I) azide to 1-methylcyclohexene is faster than to cyclohexene. intermediates in these reactions are discussed.

引用

页码：180 / 184

页数：5

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