STRUCTURE ELUCIDATION OF TETRAZOLO[5,1-C]BENZO-AS-TRIAZINE - INTERESTING TERNARY EQUILIBRIUM OF TETRAZOLE-AZIDE SYSTEMS

被引：38

作者：

MESSMER, A

HAJOS, G

TAMAS, J

NESZMELYI, A

机构：

[1] Central Research Institute for Chemistry of the Hungarian Academy of Sciences

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 11期

关键词：

D O I：

10.1021/jo01325a016

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title equilibrium has been studied by UV, MS, and NMR. The originally proposed angular structure tetrazolo[5, 1-c]benzo-as-triazine (3) is the major component both in solution and in the solid state. By means of 13C NMR spectroscopy, an interesting ternary equilibrium was detected in Me2SO which involves 3 as the main component (64%), in addition to 2 (25%) and 4 present in smaller amounts (10%). © 1979, American Chemical Society. All rights reserved.

引用

页码：1823 / 1825

页数：3

共 8 条

[1] TETRAZOLO[1,5-B]-1,2,4-TRIAZINES - SYNTHESES AND STRUCTURE DETERMINATION [J].