EQUILIBRIUM-CONSTANTS FOR THE FORMATION OF CU(I) HALIDE-COMPLEXES

被引：31

作者：

SHARMA, VK ^{[1
]}

MILLERO, FJ ^{[1
]}

机构：

[1] UNIV MIAMI,ROSENSTIEL SCH MARINE & ATMOSPHER SCI,4600 RICKENBACKER CAUSEWAY,MIAMI,FL 33149

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1990年 / 19卷 / 04期

关键词：

complexes; CuBr; CuCl; Equilibrium constants; Pitzer equations; spectral data;

D O I：

10.1007/BF00648142

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The stoichiometric equilibrium constants, K 3 *, for the formation of CuX 3 2- from CuX 2 - +X- where X=Cl and Br, have been determined from spectral measurements. The measurements were made in NaCl and NaBr solutions from I=0.5 to 6.0m at 5, 25 and 45°C. The measured constants were extrapolated to infinite dilution using the Pitzer equations. The Pitzer parameters, β0, β1 and Cφ, for the interaction of Na+ with CuX 2 - and CuX 3 2- are briefly discussed. © 1990 Plenum Publishing Corporation.

引用

页码：375 / 390

页数：16

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