A SYNTHON FOR C2 POLYCYCLIC 1,4,5,8-TETRAHYDRONAPHTHALENES VIA DOUBLE DIELS-ALDER CYCLOADDITION

被引：11

作者：

DELUCCHI, O ^{[1
]}

COSSU, S ^{[1
]}

机构：

[1] UNIV SASSARI,DIPARTIMENTO CHIM,I-07100 SASSARI,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 15期

关键词：

D O I：

10.1039/c39920001089

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Chloro-1,4-benzodithiin-S,S'-tetroxide 1 is a synthon for C2 because its Diels-Alder adducts, after dehydrochlorination, react further with another molecule of diene and the resulting product can be desulfonylated into the same hydrocarbons that would have formed from C2.

引用

收藏

页码：1089 / 1090

页数：2

相关论文

共 12 条

[1]

AZZENA U, 1989, GAZZ CHIM ITAL, V119, P357

[2]

COSSU S, 1990, GAZZ CHIM ITAL, V120, P569

[3] ANTI-1,4,5,8-TETRAHYDRO-1,4-5,8-DIMETHANONAPHTHALENE (SESQUINORBORNADIENE), A MOLECULE WITH 3 PARALLEL, COPLANAR, AND INTERACTING DOUBLE-BONDS [J].

DELUCCHI, O ;

LICINI, G ;

PASQUATO, L .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (07) :418-419

[4] SYNTHESIS OF POLYCYCLIC ALKENES VIA REDUCTIVE ELIMINATION OF BETA-DICYANO DERIVATIVES - A FACILE PREPARATION OF ANTI-SESQUINORBORNENE AND RELATED MOLECULES [J].

DELUCCHI, O ;

PICCOLROVAZZI, N ;

MODENA, G .

TETRAHEDRON LETTERS, 1986, 27 (36) :4347-4350

[5]

DELUCCHI O, 1987, GAZZ CHIM ITAL, V117, P401

[6]

LUCCHI OD, 1984, TETRAHEDRON, V40, P2585

[7] HYPERSTABLE OLEFINS - FURTHER CALCULATIONAL EXPLORATIONS AND PREDICTIONS [J].

MCEWEN, AB ;

SCHLEYER, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (14) :3951-3960

[8] 1,4-BENZODITHIIN 1,1,4,4-TETRAOXIDE AS DIENOPHILE [J].

NAKAYAMA, J ;

NAKAMURA, Y ;

HOSHINO, M .

HETEROCYCLES, 1985, 23 (05) :1119-1122

[9] CONSEQUENCES OF FIXING 3 PARALLEL COPLANAR DOUBLE-BONDS IN CLOSE PROXIMITY WITH DIFFERENT GEOMETRIES - SYNTHESIS AND SPECTRAL PARAMETERS OF SYN-SESQUINORBORNATRIENE AND ANTI-SESQUINORBORNATRIENE [J].

PAQUETTE, LA ;

KUNZER, H ;

GREEN, KE ;

DELUCCHI, O ;

LICINI, G ;

PASQUATO, L ;

VALLE, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (12) :3453-3460

[10] BIS(ARYLSULPHONYL)ACETYLENES [J].

PASQUATO, L ;

DELUCCHI, O ;

KROTZ, L .

TETRAHEDRON LETTERS, 1991, 32 (19) :2177-2178