P-31 NMR structure correlations for phosphonocarboxylic acids and esters

被引:9
作者
OlagnonBourgeot, S
Chastrette, F
Wilhelm, D
机构
[1] UNIV LYON 1,CHIM ORGAN PHYS & SYNTH LAB,F-69622 VILLEURBANNE,FRANCE
[2] HOECHST AG,SOC FRANCAISE,CRA,F-92240 STAINS,FRANCE
关键词
NMR; P-31; structure-delta correlations; phosphonocarboxylic acid esters; esterification;
D O I
10.1002/mrc.1260331205
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
P-31 chemical shift-structure correlations were established from methyl and ethyl esters of simple phosphonocarboxylic acids. The influence of solvent, acidity, function and neighbourhood of phosphorus was studied, The correlations could be extended and led to the identification of esters obtained when a series of phosphonocarboxylic acids were reacted with alcohols-reactions which were designed as models of cellulose cross-linking by these acids.
引用
收藏
页码:971 / 976
页数:6
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