SI[(ME2P)2C(SIME3)]2, A STABLE SIGMA-BONDED COMPOUND CONTAINING DIVALENT SILICON

被引：89

作者：

KARSCH, HH

KELLER, U

GAMPER, S

MULLER, G

机构：

[1] Anorganisch-Chemisches Institut, Technischen Universität München, Garching, D-8046

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 03期

关键词：

D O I：

10.1002/anie.199002951

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New reaction paths in silicon chemistry could be opened up by the title compound 1, in which the diphosphinomethide ligands are σ‐bonded to the SiII center. Like the analogous germanium and tin compounds, 1 is pseudotrigonal‐bipyramidal; remarkably, however, 1 is structurally similar to the tin compound. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

收藏

页码：295 / 296

页数：2

相关论文

共 28 条

[1] REACTION OF DIMESITYLSILYLENE IN A CRYOGENIC OXYGEN MATRIX - IR SPECTROSCOPIC OBSERVATION OF A SILYLENE OXYGEN ADDUCT [J].

AKASAKA, T ;

NAGASE, S ;

YABE, A ;

ANDO, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (18) :6270-6272

[2] THE 1ST SPECTROSCOPIC DETECTION OF SILAYLIDES IN THE REACTION OF DIMESITYLSILYLENE WITH P, S, AND N HETEROATOM-CONTAINING SUBSTRATES - THE STABILITY OF SILAYLIDES [J].

ANDO, W ;

SEKIGUCHI, A ;

HAGIWARA, K ;

SAKAKIBARA, A ;

YOSHIDA, H .

ORGANOMETALLICS, 1988, 7 (02) :558-559

[3] THE REACTION OF DIMETHYLSILYLENE WITH CARBON-MONOXIDE IN LOW-TEMPERATURE MATRICES [J].

ARRINGTON, CA ;

PETTY, JT ;

PAYNE, SE ;

HASKINS, WCK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (18) :6240-6241

[4] CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .115. SYNTHESIS AND PROPERTIES OF THE TETRAPHOSPHA-SILASPIRO[2.2]PENTANE (PBUT)2SI(PBUT)2 [J].

BAUDLER, M ;

PONTZEN, T .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1982, 491 (08) :27-33

[5]

DEUBELLY B, 1988, THESIS TU MUNCHEN

[6] LASER PHOTOLYSIS OF SILYLENE PRECURSORS [J].

GASPAR, PP ;

HOLTEN, D ;

KONIECZNY, S ;

COREY, JY .

ACCOUNTS OF CHEMICAL RESEARCH, 1987, 20 (09) :329-336

[7]

GASPAR PP, 1985, REACT INTERMED, V3, P335

[8] PROTONATION OF DECAMETHYLSILICOCENE [BIS(PENTAMETHYLCYCLOPENTADIENYL)SILICON] [J].

JUTZI, P ;

HOLTMANN, U ;

BOGGE, H ;

MULLER, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (04) :305-306

[9] DECAMETHYLSILICOCENE - SYNTHESIS AND STRUCTURE [J].

JUTZI, P ;

KANNE, D ;

KRUGER, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (02) :164-164

[10]

Jutzi P, 1986, ANGEW CHEM, V98, P163