Reactions of the perfluoroalkylnitriles. III. Perfluoroalkylhydrazidines and perfluoroalkyl-N-aminotriazoles

被引：41

作者：

Brown, Henry C. ^{[1
]}

Pilipovich, Donald

机构：

[1] Univ Florida, Dept Chem Engn, Gainesville, FL 32611 USA

[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1960年 / 82卷 / 17期

关键词：

D O I：

10.1021/ja01502a061

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Perfluoroalkylnitriles, RFCN, in which R-F = C3F7, C4F9, C5F11, or C7F15 were treated with hydrazine under mild conditions, to produce perfluoroalkylhydrazidines, RFC(NH2):NNH2. These compounds are believed to be the first reported examples of free, unsubstituted hydrazidines. Perfluoroacetonitrile and perfluoropropionitrile with hydrazine yielded a secondary product believed to be the 1-N-amino-2,5-bis-(perfluoroalkyl)-triazole. unsym-Dimethylhydrazine with perfluoroalkylnitriles produced N-substituted hydrazines in all examples.

引用

页码：4700 / 4703

页数：4

共 8 条

[1]

ANGELI A, 1893, CHIM, V23, P101

[2]

HUSTED D, 1954, Patent No. 2676985

[3] PERFLUORO DIBASIC ACIDS AND DERIVATIVES [J].

MCBEE, ET ;

WISEMAN, PA ;

BACHMAN, GB .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1947, 39 (03) :415-417

[4]

MIGRIDICHIAN V, 1947, CHEM ORGANIC CYANOGE, P73

[5] Announcements from the chemical institute of the University of Heidelberg. 159. The effect of dehydrated hydrazine from nitriles [J].

Muller, E ;

Herrdegen, L .

JOURNAL FUR PRAKTISCHE CHEMIE-LEIPZIG, 1921, 102 (4/7) :113-155

[6]

Pinner A., 1893, BER DTSCH CHEM GES, V26, P2126, DOI [10.1002/cber.189302602188, DOI 10.1002/CBER.189302602188]

[7] REACTIONS OF PERFLUORONITRILES .1. SYNTHESIS OF DERIVATIVES OF PERFLUOROAMIDINES, N-SUBSTITUTED PERFLUOROAMIDINES AND PERFLUOROTHIOAMIDES [J].

REILLY, WL ;

BROWN, HC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (23) :6032-6034

[8] REACTIONS OF THE PERFLUORONITRILES .2. SYNTHESES OF 2,4,6-TRIS(PERFLUOROALKYL)- 1,3,5-TRIAZINES [J].

REILLY, WL ;

BROWN, HC .

JOURNAL OF ORGANIC CHEMISTRY, 1957, 22 (06) :698-700

← 1 →