ISOLATION OF THE 1ST MIXED METHOXY-BRIDGED AND CHLORO-BRIDGED BINUCLEAR PLATINUM COMPLEX

被引：17

作者：

CLARK, HC

GOEL, AB

机构：

[1] Guelph-Waterloo Centre for Graduate Work in Chemistry, University of Guelph, Guelph, Ont. N1G 2W1, Guelph Campus

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 178卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0022-328X(00)94239-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first methoxyplatinum(II) complex, a stable binuclear complex containing bridging methoxy and chloro groups as well as metalated t-butylphosphine, [Pt2(μ-Cl)(μ-OCH3)(t-BU2PCMe2CH2)2], has been prepared by treating [Pt2Cl2(t-BU2PCMe2CH2)2] with sodium hydroxide in methanol. A symmetrical structure is proposed on the basis of 1H and 31P NMR spectroscopic data. © 1979.

引用

页码：C27 / C29

页数：3

共 23 条

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