THE REACTION OF TERMINAL PHOSPHINIDENE COMPLEXES WITH ELECTRON-RICH ALKYNES - A NEW APPROACH TO THE PHOSPHOLE RING

被引：14

作者：

HUY, NHT

MATHEY, F

机构：

[1] Laboratoire de Chimie du Phosphore et des Metaux de Transition DCPH, Ecole Poly technique

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1990年 / 47卷 / 3-4期

关键词：

(phosphine)pentacarbonyl-tungsten complexes; Phosphinidenes; phospholes; 2 + 2+1] cycloadditions;

D O I：

10.1080/10426509008038004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of electron-rich alkynes such as ethoxyacetylene or propynyldiethylamine with a transient terminal phosphinidene complex such as [PhP=W(CO)5] directly yields the corresponding phosphole complexes via a formal [2 + 2 + 1] cycloaddition involving two molecules of alkyne and one phosphorus center. © 1990 Gordon and Breach Science Publishers, Inc. © 1990, Taylor & Francis Group, LLC. All rights reserved.

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页码：477 / 481

页数：5

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