AN UNUSUAL REARRANGEMENT OF A CAGE DIKETONE MONOTOSYLHYDRAZONE - A NEW FRAGMENTATION OF THE PCUD SKELETON

被引：5

作者：

COXON, JM

FONG, ST

STEEL, PJ

机构：

[1] Department of Chemistry, University of Canterbury, Christchurch

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 51期

关键词：

D O I：

10.1016/S0040-4039(00)88521-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cage diketone monotosylhydrazone 3 undergoes rearrangement with double alpha-cleavage of the cage skeleton to give a product, 4, which formally corresponds to insertion of cyclopentadiene between the rings of naphthoquinone.

引用

页码：7479 / 7482

页数：4

共 7 条

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SYNTHETIC COMMUNICATIONS, 1989, 19 (3-4) :585-596

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