PROTON CONDUCTING POLYMER ELECTROLYTE - THE NYLON 6-1O/H3PO4 BLENDS

被引：38

作者：

GRONDIN, J ^{[1
]}

RODRIQUEZ, D ^{[1
]}

LASSEGUES, JC ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CNRS,SPECT MOLEC & CRISTALLINE LAB,URA 124,F-33405 TALENCE,FRANCE

来源：

SOLID STATE IONICS | 1995年 / 77卷

关键词：

PROTON CONDUCTOR; POLYMER ELECTROLYTE; NYLON;

D O I：

10.1016/0167-2738(94)00290-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Anhydrous Nylon 6-10, xH(3)PO(4) films have been studied by infrared and impedance spectroscopies. The CONH/acid interactions evolve from strong hydrogen bonding to protonation depending on acid concentration and temperature. Protonic conductivity reaches a value as high as 10(-3) S/cm at 25 degrees C for Nylon 6-10, 2.5 H3PO4.

引用

页码：70 / 75

页数：6

共 24 条

[1] THE INFRA-RED SPECTRA AND MOLECULAR CONFIGURATIONS OF POLYAMIDES
CANNON, CG
[J]. SPECTROCHIMICA ACTA, 1960, 16 (03): : 302 - 319
[2] CHIN DT, 1969, J APPL ELECTROCHEM, V19, P95
[3] INFRARED SPECTROSCOPY OF AMIDE AND CARBOXYLIC ACID INTERACTIONS . HYDROGEN BONDING AND PROTONATION
COMBELAS, P
CRUEGE, F
LASCOMBE, J
QUIVORON, C
REYLAFON, M
[J]. JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1969, 66 (04) : 668 - &
[4] PROTONATED CARBONYL GROUPS .7. N-ACETYLMORPHOLINE SALTS
COOK, D
[J]. SPECTROCHIMICA ACTA, 1966, 22 (03): : 419 - &
[5] NMR, CONDUCTIVITY AND NEUTRON-SCATTERING INVESTIGATION OF IONIC DYNAMICS IN THE ANHYDROUS POLYMER PROTONIC CONDUCTOR PEO(H3PO4)X
DONOSO, P
GORECKI, W
BERTHIER, C
DEFENDINI, F
POINSIGNON, C
ARMAND, MB
[J]. SOLID STATE IONICS, 1988, 28 : 969 - 974
[6] INFRARED STUDIES OF CHAIN FOLDING IN POLYMERS .10. POLYCAPROLACTAM
FRAYER, PD
KOENIG, JL
LANDO, JB
[J]. JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1972, B 6 (01): : 129 - &
[7] THE MECHANISM OF ELECTRICAL CONDUCTION IN FUSED PHOSPHORIC AND TRIDEUTEROPHOSPHORIC ACIDS
GREENWOOD, NN
THOMPSON, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1959, (NOV): : 3485 - 3492
[8] HAURIE M, 1965, J CHIM PHYS, V62, P137, DOI 10.1051/jcp/1965620137
[9] THE STRUCTURE OF PROTONATED AMIDES AND UREAS AND THEIR THIO ANALOGUES
JANSSEN, MJ
[J]. SPECTROCHIMICA ACTA, 1961, 17 (05): : 475 - 485
[10] SINGLE-CRYSTAL NEUTRON-DIFFRACTION STUDY OF UREA-PHOSPHORIC ACID
KOSTANSEK, EC
BUSING, WR
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1972, B 28 (AUG15): : 2454 - +

← 1 2 3 →