TRAPPING OF TRANSLOCATED RADICALS BY TETRATHIAFULVALENE RADICAL-CATION

被引：23

作者：

MURPHY, JA

ROOME, SJ

机构：

[1] Department of Chemistry, University of Nottingham, Nottingham NG7 2RD, University Park

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 11期

关键词：

D O I：

10.1039/p19950001349

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl radicals are generated by electron transfer from tetrathiafulvalene to arenediazonium salts. The aryl radicals are translocated into alkyl radicals which undergo a C-S or C-C bond formation to tetrathiafulvalene radical cation, depending on the nucleophilicity/electrophilicity of the translocated carbon radical.

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页码：1349 / 1358

页数：10

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