OXYGEN-TRANSFER IN THE REACTIONS OF HYPOFLUOROUS ACID WITH AQUEOUS-SOLUTIONS

被引:18
作者
APPELMAN, EH
THOMPSON, RC
ENGELKEMEIR, AG
机构
[1] Chemistry Division Argonne National Laboratory, Argonne
关键词
D O I
10.1021/ic50194a001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Oxygen-18 tracer studies have shown that the reactions of HO*F with H2O and with aqueous HSO4- and Cr(NH3)5N32+ lead to transfer of oxygen with formation of HOO*H, O3SOO*H-, and Cr(NH3)5NO*2+, respectively. Transfer is incomplete in the case of dilute (0.4 M) bisulfate solutions. © 1979, American Chemical Society. All rights reserved.
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页码:909 / 911
页数:3
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