Observation of fluorescence originating from transitions between excited electronic states in a large molecule

被引:38
作者
Rentzepis, P. M. [1 ]
Jortner, J. [2 ]
Jones, R. P. [1 ]
机构
[1] Bell Telephone Labs, Murray Hill, NJ USA
[2] Tel Aviv Univ, Dept Chem, IL-69978 Tel Aviv, Israel
关键词
D O I
10.1016/0009-2614(70)80094-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this note we report the observation of emission of the azulene molecule in the region of 13 200 cm(-1). characterized by a quantum yield of 10(-7), which is assigned to the (1)A(1) (2) -> B-1(1), (1) radiative transition between excited electronic states of a large molecule.
引用
收藏
页码:599 / 602
页数:4
相关论文
共 22 条
[1]   ANOMALOUS LIGHT EMISSION OF AZULENE [J].
BEER, M ;
LONGUETHIGGINS, HC .
JOURNAL OF CHEMICAL PHYSICS, 1955, 23 (08) :1390-1391
[2]  
BERLMAN M, HDB MOL FLUORESCENCE
[3]   On the fluorescence anomaly of azulene [J].
Binsch, G. ;
Hexlbronner, E. ;
Jankow, R. ;
Schmidt, D. .
CHEMICAL PHYSICS LETTERS, 1967, 1 (04) :135-138
[4]   INTRAMOLECULAR RADIATIONLESS TRANSITIONS [J].
BIXON, M ;
JORTNER, J .
JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (02) :715-&
[5]  
BIXON M, IN PRESS J CHEM PHYS
[6]   Direct measurement of S-T crossing relaxation time in azulenes [J].
Drent, E. ;
Van Der Deijl, G. Makkes ;
Zandstra, P. J. .
CHEMICAL PHYSICS LETTERS, 1968, 2 (08) :526-528
[7]   RADIATIVE DECAY OF POLYATOMIC MOLECULES [J].
FREED, KF ;
JORTNER, J .
JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (07) :2916-&
[8]  
HERZBERG G, 1954, SPECTRA DIATOMIC MOL
[9]  
JOHNSON, 1964, J MOL SPECTROSC, V14, P198
[10]  
LOGAN LM, IN PRESS