STABILIZATION OF ORGANO-SILVER(I) COMPOUNDS, AND THEIR APPLICATION IN ORGANIC-SYNTHESIS

被引：28

作者：

WESTMIJZE, H

KLEIJN, H

VERMEER, P

机构：

[1] Department of Organic Chemistry, State University of Utrecht, Utrecht

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 172卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)92371-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The favourable influence of lithium bromide on the thermal stability of organosilver(I) compounds is described. The stabilized silver(I) compounds have been brought into reaction with conjugated enynes; the regiochemistry of the reactions appears to depend on steric factors. A comparison is presented of the behaviour of the silver(I) and the corresponding copper(I) reagents in this reaction. © 1979.

引用

页码：377 / 383

页数：7

共 14 条

[1]

BAHR G, 1970, HOUBEN WEYL METHODEN, V13, P763

[2]

BEVERWIJK CD, 1970, ORGANOMET CHEM REV A, V5, P215

[3]

COASTA G, 1956, GAZZ CHIM ITAL, V86, P77

[4] COPPER(I)-ARYL BONDS IN CLUSTER COMPLEXES - STRUCTURE OF [CU(2-ME2 NC6H4)]4(CUBR)2.1.5C6H6 [J].

GUSS, JM ;

MASON, R ;

NOLTES, JG ;

THOMAS, KM ;

VANKOTEN, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 40 (02) :C79-&

[5]

HOFSTEE HK, 1978, THESIS U UTRECHT

[6]

JUKES AE, 1974, ADV ORGANOMETALLIC C, V12, P215

[7] STEREOSPECIFIC ADDITION OF ORGANOCOPPER(I) REAGENTS TO 1-ALKYNYLPHOSPHINES - NEW EXAMPLE OF ALPHA-HETERO-SUBSTITUTED VINYLCOPPER(I) COMPOUNDS [J].

MEIJER, J ;

WESTMIJZE, H ;

VERMEER, P .

RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1976, 95 (05) :102-104

[8]

NORMANT JF, 1972, SYNTH-INT J METHODS, P63

[9]

POSNER GH, 1975, ORG REACTIONS, V22, pCH2

[10]

POSNER GH, 1972, ORG REACTIONS, V19, pCH1

← 1 2 →