SOME REACTIONS OF STABLE OZONIDE DERIVED FROM 4H-CYCLOPENTA[DEF]PHENANTHRENE

被引：12

作者：

YOSHIDA, M ^{[1
]}

KADOKURA, A ^{[1
]}

SUZUKI, K ^{[1
]}

MINABE, M ^{[1
]}

机构：

[1] UTSUNOMIYA UNIV,FAC ENGN,DEPT IND CHEM,UTSUNOMIYA 32131,JAPAN

来源：

TETRAHEDRON | 1979年 / 35卷 / 19期

关键词：

D O I：

10.1016/0040-4020(79)80116-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The ozonization of 4H-cyclopenta[def]phenanthrene gave exclusively a stable monomeric ozonide in a pure crystalline state. Reduction of the ozonide afforded the corresponding dialdehyde, diol, and lactone by treatment with triphenylphosphine, lithium aluminium hydride, and sodium sulfite, respectively. Photo-irradiation of the ozonide converted it into an acid anhydride. The corresponding aldehyde acid was obtained by pyrolysis of the ozonide. © 1979.

引用

页码：2237 / 2241

页数：5

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