PYROLYSIS-GAS CHROMATOGRAPHIC CHARACTERIZATION OF HIGHLY ALTERNATING COPOLYMERS CONTAINING STYRENE AND TETRACYANOQUINODIMETHAN, METHYL ACRYLATE, ACRYLONITRILE, OR METHYL-METHACRYLATE UNITS

被引：26

作者：

TSUGE, S

KOBAYASHI, T

SUGIMURA, Y

NAGAYA, T

TAKEUCHI, T

机构：

[1] Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University, Nagoya

来源：

MACROMOLECULES | 1979年 / 12卷 / 05期

关键词：

D O I：

10.1021/ma60071a041

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A method of characterizing configurational microstructures of highly alternating copolymers was proposed using pyrolysis gas chromatography with a high-resolution glass capillary column. By this method, almost perfectly ordered microstructures of styrene (St)-tetracyanoquinodimethan (TCNQ) alternating copolymer were confirmed, and the degree of disordered configuration was estimated for various highly alternating copolymers such as St-methyl methacrylate (MA), St-acrylonitrile (AN), and St-methyl methacrylate (MMA) copolymers. © 1979, American Chemical Society. All rights reserved.

引用

页码：988 / 992

页数：5

共 15 条

[1]

BLOUIN FA, 1973, POLYM PREPRINTS A PC, V14, P25

[2] DETERMINATION OF AN ALTERNATING MONOMER SEQUENCE DISTRIBUTION IN PROPYLENE-BUTADIENE COPOLYMERS USING C-13 NUCLEAR MAGNETIC-RESONANCE [J].