X-RAY-DIFFRACTION EXAMINATION OF ORTHO-CARBORANES WITH TERT-BUTYL AND TRIMETHYLSILYL SUBSTITUENTS

被引：1

作者：

KIRILLOVA, NI

KLIMOVA, TV

STRUCHKOV, YT

STANKO, VI

机构：

[1] Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 11期

关键词：

D O I：

10.1007/BF00951702

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By a complete x-ray diffraction examination of 1-tert-butyl-o-carborane (I) and 1-trimethylsilyl-2-methyl-o-carborane (II), it was found that the bonds between the substituants and the icosahedral skeleton are elongated. The tert-butyl substituent in (I) has a screened orientation with respect to the nearest pentagonal fragment, and the trimethylsilyl substituent in (II), a screened orientation with respect to the boron atoms. © 1980 Plenum Publishing Corporation.

引用

页码：2296 / 2301

页数：6

共 13 条

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