TACTIC POLY(CROWN ETHER)S WITH PENDANT BENZOCROWN ETHERS

被引：30

作者：

KIMURA, K

TAMURA, H

MAEDA, T

SHONO, T

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Osaka, 565, Yamada-kami, Suita

来源：

POLYMER BULLETIN | 1979年 / 1卷 / 06期

关键词：

D O I：

10.1007/BF00284410

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Tactic and atactic poly(crown ether)s, poly(methacryloyloxymethylbenzo-15-crown-5), were synthesized by polymer reaction of the respective poly(methacrylic acid) with chloromethylbenzo-15-crown-5 and radical polymerization of methacryloyloxymethylbenzo-15-crown-5. By solvent extraction of alkali metal picrates with these poly(crown ether)s, the isotactic poly(crown ether) was found to be a little more selective for K+ and Rb+ than the syndiotactic and atactic ones. © 1979 Springer-Verlag.

引用

页码：403 / 407

页数：5

共 6 条

[1] NEW POLY(CROWN ETHER) AND BIS(CROWN ETHER) AS EXTRACTING REAGENTS
KIMURA, K
MAEDA, T
SHONO, T
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[2] KOPOLOW S, 1973, MACROMOLECULES, V6, P133
[3] CRYSTAL-STRUCTURES OF COMPLEXES BETWEEN ALKALI-METAL SALTS AND CYCLIC POLYETHERS .5. 1-2 COMPLEX FORMED BETWEEN POTASSIUM IODIDE AND 2,3,5,6,8,9,11,12-OCTAHYDRO-1,4,7,10,13-BENZOPENTAOXACYCLO-PENTADECIN (BENZO-15-CROWN-5)
MALLINSON, PR
TRUTER, MR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1972, (12): : 1818 - +
[4] CRYSTALLINE SALT COMPLEXES OF MACROCYCLIC POLYETHERS
PEDERSEN, CJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (02) : 386 - &
[5] PEDERSEN CJ, 1968, FED PROC, V27, P1305
[6] Yuki H., 1970, POLYM J, V1, P36

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