NOVEL METAL THIOLATES - [CO2(SC3H7)5]-, THE 1ST COMPLEX WITH FACE-SHARING MS4 TETRAHEDRA

被引：20

作者：

HENKEL, G

WEISSGRABER, S

机构：

[1] Festkörperchemie, Universität Duisburg, D-W-4100

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 10期

关键词：

D O I：

10.1002/anie.199213681

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A trigonal bipyramid made up of sulfur atoms with two cobalt atoms in the cavity, or two face-sharing CoS4 tetrahedra-both are apt descriptions of the structure of the title anion 1. The Co-Co distance is remarkably short (2.491 (1) angstrom). and the isopropyl groups of the three bridging thiolato ligands have a paddle-wheel-type arrangement about a C3 axis. Complex 1 is obtained from cobalt(II) nitrate and sodium propane-2-thiolate and can be isolated as the ammonium salt.

引用

收藏

页码：1368 / 1369

页数：2

相关论文

共 10 条

[1] SYNTHESIS AND STEREOCHEMISTRY OF METAL(II) THIOLATES OF THE TYPES [M(SR)4]2-, [M2(SR)6]2-, AND [M4(SR)10]2- (M = FE(II), CO(II) [J].

HAGEN, KS ;

HOLM, RH .

INORGANIC CHEMISTRY, 1984, 23 (04) :418-427

[2] SYNTHESIS AND STRUCTURE OF [PH4P]2[HG3(SCH2C6H4CH2S)4].6MEOH A NOVEL TRINUCLEAR MERCURY THIOLATE COMPLEX WITH A TRIPLY BRIDGING SULFUR ATOM [J].

HENKEL, G ;

BETZ, P ;

KREBS, B .

INORGANICA CHIMICA ACTA, 1987, 134 (02) :195-196

[3] [HG3(SCH2CH2S)4]2- AND ([HG2(SCH2CH2S)3]2-)-NORMAL - EXAMPLES OF TRINUCLEAR AND QUASI-ISOLATED BINUCLEAR POLYMERIC MERCURY THIOLATE ANIONS [J].

HENKEL, G ;

BETZ, P ;

KREBS, B .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (21) :1498-1499

[4] TRANSITION-METAL THIOLATES - FROM MOLECULAR FRAGMENTS OF SULFIDIC SOLIDS TO MODELS FOR ACTIVE-CENTERS IN BIOMOLECULES [J].

KREBS, B ;

HENKEL, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1991, 30 (07) :769-788

[5]

Krebs B, 1991, ANGEW CHEM, V103, P785

[6] SYNTHESIS AND STRUCTURAL SYSTEMATICS OF ETHANE-1,2-DITHIOLATO COMPLEXES [J].

RAO, CP ;

DORFMAN, JR ;

HOLM, RH .

INORGANIC CHEMISTRY, 1986, 25 (04) :428-439

[7] TRANSITION-METAL COMPLEXES WITH SULFUR LIGANDS .7. SYNTHESIS AND STRUCTURE OF THE BENZENEDITHIOLATO-IRON COMPLEXES [ASPH4]2[FE(S2C6H4)2] AND [FE(S2C6H4)(PME3)3] [J].

SELLMANN, D ;

KLEINEKLEFFMANN, U ;

ZAPF, L ;

HUTTNER, G ;

ZSOLNAI, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 263 (03) :321-331

[8] NICKEL THIOLATE CHEMISTRY BASED ON CHELATING LIGANDS - CONTROLLING THE COURSE OF SELF-ASSEMBLY REACTIONS VIA LIGAND BITE DISTANCES - SYNTHESIS, STRUCTURES, AND PROPERTIES OF THE HOMOLEPTIC COMPLEXES [NI3(SCH2C6H4CH2S)4]2-, [NI3(SCH2CH2S)4]2-, AND [NI6(SCH2CH2CH2S)7]2- [J].

TREMEL, W ;

KRIEGE, M ;

KREBS, B ;

HENKEL, G .

INORGANIC CHEMISTRY, 1988, 27 (22) :3886-3895

[9] THIOLATE CHEMISTRY OF THE IRON GROUP ELEMENTS - SYNTHESIS AND STRUCTURE OF THE COMPLEXES [CO2(ORTHO-(SCH2)2C6H4)3]2-THETA AND [NI3(ORTHO-(SCH2)2C6H4)4]2-THETA [J].

TREMEL, W ;

KREBS, B ;

HENKEL, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (08) :634-635

[10]

Tremel W., 1984, ANGEW CHEM, V96, P604