LANTHANIDE COMPLEXES OF MACROCYCLIC AND MACROBICYCLIC N-OXIDES - LIGHT-CONVERTING SUPRAMOLECULAR DEVICES

被引：51

作者：

PIETRASZKIEWICZ, M

KARPIUK, J

ROUT, AK

机构：

[1] Institute of Physical Chemistry, Polish Academy of Sciences, 01224, Warsaw

来源：

PURE AND APPLIED CHEMISTRY | 1993年 / 65卷 / 03期

关键词：

D O I：

10.1351/pac199365030563

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several ligands of various topology: macromonocyclic, macrobicyclic, cylindrical, acyclic, and pendant-type bearing photoactive units: 3,3'-biisoquinoline-2,2--dioxide, methyl-2-pyridine and dibenzoylmethane display an efficient energy transfer from the excited triplet state of the ligand to the resonance level of the lanthanide cation. The lanthanide complexes are thus highly luminescent. The Eu(III) cryptate of 3 exhibits the highest quantum yield for the Eu(III) emission (0.17).

引用

收藏

页码：563 / 566

页数：4

相关论文

共 20 条

[1] SYNTHESIS AND CHARACTERIZATION OF THE SODIUM AND LITHIUM CRYPTATES OF MACROBICYCLIC LIGANDS INCORPORATING PYRIDINE, BIPYRIDINE, AND BIISOQUINOLINE UNITS [J].

ALPHA, B ;

ANKLAM, E ;

DESCHENAUX, R ;

LEHN, JM ;

PIETRASKIEWICZ, M .

HELVETICA CHIMICA ACTA, 1988, 71 (05) :1042-1052

[2] ANTENNA EFFECT IN LUMINESCENT LANTHANIDE CRYPTATES - A PHOTOPHYSICAL STUDY [J].

ALPHA, B ;

BALLARDINI, R ;

BALZANI, V ;

LEHN, JM ;

PERATHONER, S ;

SABBATINI, N .

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1990, 52 (02) :299-306

[3] ENERGY-TRANSFER LUMINESCENCE OF EUROPIUM(III) AND TERBIUM(III) CRYPTATES OF MACROBICYCLIC POLYPYRIDINE LIGANDS [J].

ALPHA, B ;

LEHN, JM ;

MATHIS, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (03) :266-267

[4] LUMINESCENCE PROPERTIES OF EU3+ AND TB3+ COMPLEXES OF BRANCHED MACROCYCLIC LIGANDS CONTAINING 4 2,2'-BIPYRIDINE UNITS [J].

BALZANI, V ;

LEHN, JM ;

VANDELOOSDRECHT, J ;

MECATI, A ;

SABBATINI, N ;

ZIESSEL, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (02) :190-191

[5] LUMINESCENCE PROPERTIES OF EU-3+ COMPLEXES OF TRIPODE AND TETRAPODE LIGANDS CONTAINING 2,2'-BIPYRIDINE UNITS [J].

BALZANI, V ;

BERGHMANS, E ;

LEHN, JM ;

SABBATINI, N ;

TERORDE, R ;

ZIESSEL, R .

HELVETICA CHIMICA ACTA, 1990, 73 (08) :2083-2089

[6]

Balzani V., 1987, SUPRAMOLECULAR PHOTO

[7]

BKOUCHEWAKSMAN I, 1991, HELV CHIM ACTA, V714, P1163

[8] LUMINESCENCE PROCESSES IN [TB SUBSET-OF BPY.BPY.BPY]3+ CRYPTATE - A LOW-TEMPERATURE SOLID-STATE STUDY [J].

BLASSE, G ;

DIRKSEN, GJ ;

SABBATINI, N ;

PERATHONER, S ;

LEHN, JM ;

ALPHA, B .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (09) :2419-2422

[9] [EU SUPERSET BPY.BPY.BPY]3+ CRYPTATE - LUMINESCENCE AND CONFORMATION [J].

BLASSE, G ;

DIRKSEN, GJ ;

VANDERVOORT, D ;

SABBATINI, N ;

PERATHONER, S ;

LEHN, JM ;

ALPHA, B .

CHEMICAL PHYSICS LETTERS, 1988, 146 (3-4) :347-351

[10] PHOTOACTIVE CRYPTANDS - CRYSTAL-STRUCTURE OF THE SODIUM CRYPTATE OF THE TRIS(PHENANTHROLINE) MACROBICYCLIC LIGAND [J].

CARON, A ;

GUILHELM, J ;

RICHE, C ;

PASCARD, C ;

ALPHA, B ;

LEHN, JM ;

RODRIGUEZUBIS, JC .

HELVETICA CHIMICA ACTA, 1985, 68 (06) :1577-1582