Osmotic and Activity Coefficients in Dilute Solutions of Ethanol in Cyclohexane from Freezing-Point Measurements

被引:20
作者
Stokes, R. H. [1 ]
机构
[1] Univ New England, Dept Phys Chem, Armidale, NSW 2351, Australia
关键词
Ethanol; osmotic coefficient; activity coefficient; freezing point; association;
D O I
10.1007/BF00650410
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The calorimeter developed in this laboratory for isothermal enthalpy-of-dilution measurements is adapted for use as an adiabatic calorimeter for freezing-point studies. Results are obtained for ethanol solutions in cyclohexane at mole fractions of ethanol from 0.001 up to 0.08. Activities calculated from the results are used to test association models.
引用
收藏
页码:671 / 681
页数:11
相关论文
共 15 条