PHOSPOROUS-CARBON-HALOGEN COMPOUNDS .13. ON THE REACTION OF TRIMETHYLSILYL-SUBSTITUTED METHYLDIPHENYLPHOSPHANES WITH TETRACHLOROMETHANE

被引：10

作者：

APPEL, R

SCHOLER, HF

机构：

[1] Anorganisch-Chemisches Institut Der Universität Bonn, Bonn, D-5300

来源：

CHEMISCHE BERICHTE-RECUEIL | 1979年 / 112卷 / 03期

关键词：

D O I：

10.1002/cber.19791120329

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On the Reaction of Trimethylsilyl‐substituted Methyldiphenylphosphanes with Tetrachloromethane In dichloromethane the [(trimethylsilyl)methyl]‐substituted phosphanes 3a, b undergo a chloroform elimination with CCl4 to give the chloromethylenediphenylphosphoranes 4a, b. The new P‐chloro ylides are remarkably stable and can be isolated as pure substances. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：1068 / 1070

页数：3

共 6 条

[1] PHOSPHORUS-CARBON-HALOGEN COMPOUNDS .12. NEW SYNTHESIS OF METHYLENEBIS(DIORGANYLPHOSPHANES) AND AN UNUSUAL DECOMPOSITION BY ALKALI-METALS
APPEL, R
GEISLER, K
SCHOLER, HF
[J]. CHEMISCHE BERICHTE-RECUEIL, 1979, 112 (02): : 648 - 653
[2] SIMPLE ROUTE TO CHLOROMETHINE-BRIDGED METHYLPHOSPHONIUM SALTS
APPEL, R
MILKER, R
RUPPERT, I
[J]. CHEMISCHE BERICHTE-RECUEIL, 1977, 110 (06): : 2385 - 2387
[3] GENERAL REACTION OF PHOSPHINES AND CARBON-TETRACHLORIDE ON NUCLEOPHILES .29. REACTIONS IN SYSTEM TRIPHENYLPHOSPHINE-CARBON TETRACHLORIDE
APPEL, R
KNOLL, F
MICHEL, W
MORBACH, W
WIHLER, HD
VELTMANN, H
[J]. CHEMISCHE BERICHTE-RECUEIL, 1976, 109 (01): : 58 - 70
[4] PHOSPHORUS-CARBON-HALOGEN COMPOUNDS .10. REACTIONS OF TRIPHENYL (TRICHLOROMETHYL) PHOSPHONIUM CHLORIDE WITH TERTIARY PHOSPHANES
APPEL, R
SCHOLER, HF
WIHLER, HD
[J]. CHEMISCHE BERICHTE-RECUEIL, 1979, 112 (02): : 462 - 467
[5] APPEL R, UNPUBLISHED
[6] Cooper B. E., 1970, J ORGANOMET CHEM, V21, P329

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