HIGHLY SELECTIVE MULTISTEP IONIZATION OF ATOMS BY LASER-RADIATION

The possibility of dramatic selectivity increase during the stepwise ionization of atoms due to selective excitation at every step has been examined. Evaluations have been made to estimate the selectivity of excitation and ionization by laser radiation of some atoms, their isotopic shifts of absorption lines being observed at several excitation steps, for instance those of U, Yb, Gd. During three-step ionization of Yb atoms in atomic beam one may obtain an excitation selectivity equal to 4.4 × 1016 cm2. © 1979.